DEPROTECTION OF 1,3-DITHIANES BY ANTIMONY PENTACHLORIDE VIA SINGLE ELECTRON-TRANSFER PROCESSES

被引：29

作者：

KAMATA, M ^{[1
]}

OTOGAWA, H ^{[1
]}

HASEGAWA, E ^{[1
]}

机构：

[1] NIIGATA UNIV,FAC SCI,DEPT CHEM,NIIGATA 95021,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 50期

关键词：

D O I：

10.1016/0040-4039(91)80123-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of 1,3-dithianes was converted to the corresponding carbonyl compounds in good yields when those substances were treated with antimony pentachloride in methylene chloride. Single electron transfer from dithianes to antimony pentachloride was proposed as an initiation step of the reaction.

引用

页码：7421 / 7424

页数：4

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