COORDINATION-COMPOUNDS OF PLATINUM(II) AND PALLADIUM(II) WITH PYRAZOLE AS A LIGAND - NEW SYNTHETIC PROCEDURES AND CHARACTERIZATION

被引：28

作者：

VANKRALINGEN, CG ^{[1
]}

RIDDER, JKD ^{[1
]}

REEDIJK, J ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,DEPT CHEM,NL-2600 GA DELFT,NETHERLANDS

来源：

TRANSITION METAL CHEMISTRY | 1980年 / 5卷 / 02期

关键词：

D O I：

10.1007/BF01396873

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a number of new coordination compounds of Pt**I**I and Pd**I**I with the nitrogen donor ligand pyrazole (PzH) is described. These compounds are cis-Pt(PzH)//2X//2, trans-Pt(PzH)//2X//2, Pt(PzH)//4X//2 multiplied by (times) n H//2O (n equals 0 or 1), Pd(PzH)//4X//2 and Pt(PzH)//4PtCl//4 where X equals Cl, Br and I. cis-Pd(PzH)//2X//2 compounds could not be obtained; trans-Pd(PzH)//2X//2 compounds seem to exist in more than one crystal form. The new compounds were characterized by chemical analyses, x-ray powder diffraction, i. r. and far-i. r. and by **1H n. m. r. spectroscopy. The metal(II) ions are in all cases coordinated in a square planar geometry.

引用

页码：73 / 77

页数：5

共 14 条

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[14]

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