STUDY OF LANTHANUM LOCAL-STRUCTURE IN MONTMORILLONITE

被引:6
作者
MUNOZPAEZ, A [1 ]
ALBA, MD [1 ]
ALVERO, R [1 ]
CASTRO, MA [1 ]
TRILLO, JM [1 ]
机构
[1] ICMSC,E-41012 SEVILLE,SPAIN
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1993年 / 32卷
关键词
D O I
10.7567/JJAPS.32S2.779
中图分类号
O59 [应用物理学];
学科分类号
摘要
The local structure of the interlamellar lanthanide ions in montmorillonite upon heating is studied. The analysis of the EXAFS data has been carried out using two model environments, that of La3+ aquocomplex and that of the lanthanum oxide. The information thus obtained is crucial in elucidating the intercalation mechanism and demonstrates the important role that XAFS techniques can play in the knowledge of the location and environment of the exchangable ions in layered silicates.
引用
收藏
页码:779 / 781
页数:3
相关论文
共 8 条
[1]  
ALBA MD, IN PRESS CLAY MINER
[2]  
DUIVENVORDEN FM, 1986, J AM CHEM SOC, V102, P6254
[3]   COORDINATION (HYDRATION) OF RARE-EARTH IONS IN AQUEOUS CHLORIDE SOLUTIONS FROM X-RAY-DIFFRACTION .2. LACL3, PRCL3, AND NDCL3 [J].
HABENSCHUSS, A ;
SPEDDING, FH .
JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (08) :3758-3763
[4]   IMPROVED ABINITIO CALCULATIONS OF AMPLITUDE AND PHASE FUNCTIONS FOR EXTENDED X-RAY ABSORPTION FINE-STRUCTURE SPECTROSCOPY [J].
MCKALE, AG ;
VEAL, BW ;
PAULIKAS, AP ;
CHAN, SK ;
KNAPP, GS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (12) :3763-3768
[5]   MOLECULAR-DYNAMICS STUDIES OF LANTHANUM CHLORIDE SOLUTIONS [J].
MEIER, W ;
BOPP, P ;
PROBST, MM ;
SPOHR, E ;
LIN, JI .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (11) :4672-4682
[6]  
MUNOZPAEZ A, 1992, J AM CHEM SOC, V114
[7]   CROSS-LINKED SMECTITES .3. SYNTHESIS AND PROPERTIES OF HYDROXY-ALUMINUM HECTORITES AND FLUORHECTORITES [J].
SHABTAI, J ;
ROSELL, M ;
TOKARZ, M .
CLAYS AND CLAY MINERALS, 1984, 32 (02) :99-107
[8]  
WELLS AF, 1962, STRUCTURAL INORGANIC, P464