LOW-SYMMETRY IN THE CRYSTAL-STRUCTURE OF (OCTAPENTYLPHTHALOCYANINATO)(METHYL) RHODIUM(III)

被引：15

作者：

CHEN, MJ ^{[1
]}

RATHKE, JW ^{[1
]}

HUFFMAN, JC ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1021/om00035a064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray structure of (octa-n-pentylphth-alocyaninato)(methyl)rhodium(III) is reported. Out-of-plane twisting of only one of the four isoindole groups in the molecule combined with a saddle-shaped distortion from planarity results in an unusual structure of low symmetry.

引用

页码：4673 / 4677

页数：5

共 18 条

[1]

ALYANOV MI, 1972, IZV VYSSH UCHEBN ZAV, V15, P1595

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF (5,10,15,20-TETRA-NORMAL-PROPYLPORPHINATO)LEAD(II) - A ROOF PORPHYRIN [J].