TERT-ALKYLATION OF KETONES AND ALDEHYDES

被引：71

作者：

REETZ, MT

MAIER, WF

机构：

[1] Fachbereich Chemie der Universität, Marburg, D-3550, Lahnberge

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 01期

关键词：

D O I：

10.1002/anie.197800481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

α‐Alkylation of carbonyl compounds (1) via the corresponding base cannot be used for the introduction of tert‐alkyl groups. This important CC coupling reaction has now been accomplished by a route involving 2, which is allowed to react with tert‐alkyl chloride in the presence of TiCl4, FeCl3, or ZnCl2. (Figure Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：48 / 49

页数：2

共 6 条

[1] THERMOLABILE HYDROCARBONS .3. STERIC ACCELERATION OF THERMOLYSIS OF HIGHLY BRANCHED ALKANES [J].