MICROWAVE TRANSITIONS OF CD2=NCN

被引：14

作者：

BAK, B

SVANHOLT, H

机构：

[1] Chemical Laboratory V, The H.C. Orsted Institute, University of Copenhagen

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)85041-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In continuation of our studies of the pyrolysis (1000°C) of (CH3)2NCN to alleged CH2=NCN (I), N-cyanoformimine, (CD3)2NCN has been prepared and pyrolyzed (1000°C) to CD2=NCN (II) as seen by its observed rotational transitions (18.6-40.0 GHz). The published rigid structural model of I and a corresponding structure of II are practically identical. © 1979.

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页码：387 / 389

页数：3

相关论文

共 8 条

[1] HCN AND HNC DIMERS - NEW AND STABLE VARIANT [J].

BAK, B ;

NIELSEN, OJ ;

SVANHOLT, H .

CHEMICAL PHYSICS LETTERS, 1978, 59 (02) :330-333

[2]

BAK B, 1978, CHEM PHYS LETT, V53, P374, DOI 10.1016/0009-2614(78)85419-0

[3] SELENOKETENE SUBSTITUTION STRUCTURE [J].

BAK, B ;

NIELSEN, OJ ;

SVANHOLT, H ;

HOLM, A .

CHEMICAL PHYSICS LETTERS, 1978, 55 (01) :36-39

[4] COMPARABLE ABINITIO CALCULATED ENERGIES OF HCNS, CNSH, NCSH AND HNCS - OPTIMIZED GEOMETRIES AND DIPOLE-MOMENTS [J].

BAK, B ;

CHRISTIANSEN, JJ ;

NIELSEN, OJ ;

SVANHOLT, H .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (08) :666-668

[5] PYROLYTIC PRODUCTION AND MICROWAVE-SPECTRA OF LIGHT AND HEAVY N-METHYLMETHYLENIMINE [J].

BAK, B ;

LARSEN, NW ;

SVANHOLT, H .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (09) :755-758

[6] DETECTION OF HC9N IN INTER-STELLAR SPACE [J].

BROTEN, NW ;

OKA, T ;

AVERY, LW ;

MACLEOD, JM ;

KROTO, HW .

ASTROPHYSICAL JOURNAL, 1978, 223 (02) :L105-L107

[7] CYANAMIDE DERIVATIVES .56. ON THE ISOMERS OF TRIMETHYLMELAMINE [J].

KITAWAKI, R ;

SUGINO, K .

JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (06) :1043-1045

[8] PREDICTION OF ROTATIONAL CONSTANTS OF POLYACETYLENE COMPOUNDS H-(C=C)N-C=N [J].

OKA, T .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1978, 72 (01) :172-174