A COMPUTER-PROGRAM FOR KINETIC-ANALYSIS OF NONISOTHERMAL THERMOGRAVIMETRIC DATA

被引：20

作者：

BEG, MAA ^{[1
]}

QAISER, MA ^{[1
]}

机构：

[1] PAKISTAN COUNCIL SCI & IND RES LABS,JAMRUD RD,PESHAWAR,PAKISTAN

来源：

THERMOCHIMICA ACTA | 1990年 / 173卷

关键词：

D O I：

10.1016/0040-6031(90)80614-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A computer program in BASIC which enables regression analysis and determination of kinetic and thermodynamic parameters from experimental TG/DTG non-isothermal thermogravimetric data is presented. This program allows the Freeman-Carroll, Horowitz-Metzger, Coats-Redfern and Doyle (modified by Zsako treatments) methods to be performed for up to 14 different solid-state rate-controlling reactions, including nth-order, Avrami-Erofeev, phase boundary movement and diffusional models. Data from the literature and the dehydration of calcium oxalate monohydrate were tested as examples of the application of this program.

引用

页码：281 / 294

页数：14

共 21 条

[1]

BROWN WE, 1980, COMPREHENSIVE CHEM K, V22, P90

[2] TESTING OF SOME DYNAMIC KINETIC-EQUATIONS [J].

CHEN, DTY .

JOURNAL OF THERMAL ANALYSIS, 1974, 6 (1-2) :109-117

[3] TESTING OF SOME DYNAMIC KINETIC-EQUATIONS .2. 2ND-ORDER REACTION [J].

CHEN, DTY ;

FONG, PH .

JOURNAL OF THERMAL ANALYSIS, 1975, 8 (02) :295-303

[4] THERMOGRAVIMETRIC ANALYSIS [J].

COATS, AW ;

REDFERN, JP .

ANALYST, 1963, 88 (105) :906-&

[5] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].

COATS, AW ;

REDFERN, JP .

NATURE, 1964, 201 (491) :68-&

[6]

DHARWADKAR SR, 1969, THERM ANAL, V2, P1049

[7]

Doyle C.D., 1961, J APPL POLYM SCI, V5, P285, DOI DOI 10.1002/APP.1961.070051506

[8] A COMPUTER-PROGRAM SYSTEM FOR KINETIC-ANALYSIS OF NON-ISOTHERMAL THERMOGRAVIMETRIC DATA .2. GENERALIZED KINETIC-ANALYSIS AND APPLICATION TO COAL PYROLYSIS [J].

ELDER, JP .

THERMOCHIMICA ACTA, 1985, 95 (01) :41-58

[9] TESTING OF SOME DYNAMIC KINETIC-EQUATIONS .3. ZERO-ORDER REACTION [J].

FONG, PH ;

CHEN, DTY .

JOURNAL OF THERMAL ANALYSIS, 1975, 8 (02) :305-312

[10] THE APPLICATION OF THERMOANALYTICAL TECHNIQUES TO REACTION KINETICS - THE THERMOGRAVIMETRIC EVALUATION OF THE KINETICS OF THE DECOMPOSITION OF CALCIUM OXALATE MONOHYDRATE [J].

FREEMAN, ES ;

CARROLL, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1958, 62 (04) :394-397

← 1 2 3 →