THE SELECTIVITIES AND THE MECHANISM ON HIGHLY EFFICIENT EPOXIDATION OF OLEFINS WITH 2,6-DISUBSTITUTED PYRIDINE N-OXIDES CATALYZED BY RUTHENIUM PORPHYRIN

被引：42

作者：

OHTAKE, H ^{[1
]}

HIGUCHI, T ^{[1
]}

HIROBE, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)92231-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several remarkable selectivities in competitive epoxidations using a ruthenium porphyrin /2,6-disubstituted pyridine N-oxide system were observed. The proposal that the active intermediate of this system differed from the trans-dioxo complex of ruthenium porphyrin was indicated.

引用

页码：2521 / 2524

页数：4

共 15 条

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