THE EFFECTS OF ARYL-HALOGENATION ON THE GAS PERMEABILITIES OF POLY(PHENOLPHTHALEIN TEREPHTHALATE) AND POLY(BISPHENOL-A PHTHALATE)

被引：9

作者：

CHERN, RT

PROVAN, CN

机构：

[1] Department of Chemical Engineering, North Carolina State University, Raleigh

来源：

JOURNAL OF MEMBRANE SCIENCE | 1991年 / 59卷 / 03期

基金：

美国国家科学基金会;

关键词：

DIFFUSION; GAS AND VAPOR PERMEATIONS; GAS SEPARATIONS; STRUCTURE PROPERTY RELATIONS; POLY(PHENOLPHTHALEIN TEREPHTHALATE); HALOGENATION OF; POLY(BISPHENOL-A PHTHALATE);

D O I：

10.1016/S0376-7388(00)80818-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Effects of aryl-halogenation on the permeability of poly(phenolphthalein terephthalate) and poly(bisphenol A phthalate) to several permanent gases are reported. Analyses based on separate solubility and diffusivity considerations are presented. The influence of reduced packing density of the polymer on the equilibrium gas sorption capacity and steady-state gas-permeability of the polymer is addressed. The results concur well with previous findings on poly(2,6-dimethyl phenylene oxide) and its aryl-brominated counterparts. Finally, the relationships among polymer chain rigidity, gas-diffusivity, gas molecular size, and permselectivity of the polymer are analyzed.

引用

页码：293 / 304

页数：12

共 21 条

[1] INDUCTION AND MEASUREMENT OF GLASSY-STATE RELAXATIONS BY VAPOR SORPTION TECHNIQUES [J].