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HYDROGEN-EXCHANGE DURING THE THERMAL-DECOMPOSITION OF DICYCLOPENTADIENYLDIMETHYLTITANIUM(IV)
被引:37
作者
:
ERSKINE, GJ
论文数:
0
引用数:
0
h-index:
0
机构:
Department of Chemistry, Queen's University, Kingston, Ont.
ERSKINE, GJ
HARTGERINK, J
论文数:
0
引用数:
0
h-index:
0
机构:
Department of Chemistry, Queen's University, Kingston, Ont.
HARTGERINK, J
WEINBERG, EL
论文数:
0
引用数:
0
h-index:
0
机构:
Department of Chemistry, Queen's University, Kingston, Ont.
WEINBERG, EL
MCCOWAN, JD
论文数:
0
引用数:
0
h-index:
0
机构:
Department of Chemistry, Queen's University, Kingston, Ont.
MCCOWAN, JD
机构
:
[1]
Department of Chemistry, Queen's University, Kingston, Ont.
来源
:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
|
1979年
/ 170卷
/ 01期
关键词
:
D O I
:
10.1016/S0022-328X(00)83189-7
中图分类号
:
O61 [无机化学];
学科分类号
:
070301 ;
081704 ;
摘要
:
A previous suggestion that cyclopentadienyl rings exchange hydrogens with methyl groups during the thermal decomposition of (C5H5)2Ti(CH3)2 is supported by additional studies. The thermal decomposition is found to proceed in two stages. The first involves an intramolecular α-elimination yielding methane and a black precipitate. In the second stage, this process is catalyzed, but in addition ring attack becomes important and slow exchange of ring and methyl hydrogens occurs. All stage two processes occur out of solution. Solid state decompositions appear to follow a closely similar path at comparable temperatures, as do photodecompositions. © 1979.
引用
收藏
页码:51 / 61
页数:11
相关论文
共 22 条
[1]
AUTOMATED THERMAL-DEGRADATION STUDIES ON SOLID SIGMA-ORGANOTRANSITION METAL-COMPLEXES - DIMETHYL-TITANOCENE, DIMETHYL-ZIRCONOCENE AND DIMETHYL-HAFNOCENE
ALT, HG
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
ALT, HG
DISANZO, FP
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
DISANZO, FP
RAUSCH, MD
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
RAUSCH, MD
UDEN, PC
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UDEN, PC
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1976,
107
(02)
: 257
-
263
[2]
AZUMA K, 1965, KOGYO KAGAKU ZASSHI, V68, P347
[3]
TITANOCENE AS AN INTERMEDIATE IN REACTIONS INVOLVING MOLECULAR-HYDROGEN AND NITROGEN
BERCAW, JE
论文数:
0
引用数:
0
h-index:
0
BERCAW, JE
BELL, LG
论文数:
0
引用数:
0
h-index:
0
BELL, LG
BRINTZIN.HH
论文数:
0
引用数:
0
h-index:
0
BRINTZIN.HH
MARVICH, RH
论文数:
0
引用数:
0
h-index:
0
MARVICH, RH
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1972,
94
(04)
: 1219
-
&
[4]
THERMAL-DECOMPOSITION OF DICYCLOPENTADIENYLTITANIUM(IV) DIARYL AND DIBENZYL COMPOUNDS
BOEKEL, CP
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
BOEKEL, CP
TEUBEN, JH
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
TEUBEN, JH
DELIEFDE.HJ
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
DELIEFDE.HJ
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1974,
81
(03)
: 371
-
377
[5]
TITANIUM, ZIRCONIUM AND HAFNIUM - ANNUAL SURVEY COVERING YEAR 1971
CALDERAZZO, F
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PISA, IST CHIM GEN & INORG, PISA 56100, ITALY
UNIV PISA, IST CHIM GEN & INORG, PISA 56100, ITALY
CALDERAZZO, F
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1973,
53
(JUN1)
: 179
-
205
[6]
COOPER NJ, 1974, CHEM COMMUN, P761
[7]
THERMAL-DECOMPOSITION OF DICYCLOPENTADIENYL-DIMETHYLTTANIUM(IV)
ERSKINE, GJ
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
ERSKINE, GJ
WILSON, DA
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
WILSON, DA
MCCOWAN, JD
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
MCCOWAN, JD
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1976,
114
(02)
: 119
-
125
[8]
The yields of some organolithium compounds by the improved procedure
Gilman, H
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Gilman, H
Zoellner, EA
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Zoellner, EA
Selby, WM
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Selby, WM
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1933,
55
: 1252
-
1257
[9]
IVIN KJ, 1978, CHEM COMMUN, P604
[10]
DYNAMIC INTERLIGAND HYDROGEN TRANSFER IN SOME ETA5-CYCLOPENTADIENYLZIRCONIUM AND ETA-5-CYCLOPENTADIENYLHAFNIUM TETRAHYDROBORATES
MARKS, TJ
论文数:
0
引用数:
0
h-index:
0
机构:
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
MARKS, TJ
KOLB, JR
论文数:
0
引用数:
0
h-index:
0
机构:
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
KOLB, JR
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1975,
97
(12)
: 3397
-
3401
←
1
2
3
→
共 22 条
[1]
AUTOMATED THERMAL-DEGRADATION STUDIES ON SOLID SIGMA-ORGANOTRANSITION METAL-COMPLEXES - DIMETHYL-TITANOCENE, DIMETHYL-ZIRCONOCENE AND DIMETHYL-HAFNOCENE
ALT, HG
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
ALT, HG
DISANZO, FP
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
DISANZO, FP
RAUSCH, MD
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
RAUSCH, MD
UDEN, PC
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01002
UDEN, PC
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1976,
107
(02)
: 257
-
263
[2]
AZUMA K, 1965, KOGYO KAGAKU ZASSHI, V68, P347
[3]
TITANOCENE AS AN INTERMEDIATE IN REACTIONS INVOLVING MOLECULAR-HYDROGEN AND NITROGEN
BERCAW, JE
论文数:
0
引用数:
0
h-index:
0
BERCAW, JE
BELL, LG
论文数:
0
引用数:
0
h-index:
0
BELL, LG
BRINTZIN.HH
论文数:
0
引用数:
0
h-index:
0
BRINTZIN.HH
MARVICH, RH
论文数:
0
引用数:
0
h-index:
0
MARVICH, RH
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1972,
94
(04)
: 1219
-
&
[4]
THERMAL-DECOMPOSITION OF DICYCLOPENTADIENYLTITANIUM(IV) DIARYL AND DIBENZYL COMPOUNDS
BOEKEL, CP
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
BOEKEL, CP
TEUBEN, JH
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
TEUBEN, JH
DELIEFDE.HJ
论文数:
0
引用数:
0
h-index:
0
机构:
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
RIJKS UNIV GRONINGEN,LAB ANORG CHEM,GRONINGEN,NETHERLANDS
DELIEFDE.HJ
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1974,
81
(03)
: 371
-
377
[5]
TITANIUM, ZIRCONIUM AND HAFNIUM - ANNUAL SURVEY COVERING YEAR 1971
CALDERAZZO, F
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PISA, IST CHIM GEN & INORG, PISA 56100, ITALY
UNIV PISA, IST CHIM GEN & INORG, PISA 56100, ITALY
CALDERAZZO, F
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1973,
53
(JUN1)
: 179
-
205
[6]
COOPER NJ, 1974, CHEM COMMUN, P761
[7]
THERMAL-DECOMPOSITION OF DICYCLOPENTADIENYL-DIMETHYLTTANIUM(IV)
ERSKINE, GJ
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
ERSKINE, GJ
WILSON, DA
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
WILSON, DA
MCCOWAN, JD
论文数:
0
引用数:
0
h-index:
0
机构:
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
QUEENS UNIV,DEPT CHEM,KINGSTON,ONTARIO,CANADA
MCCOWAN, JD
[J].
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
1976,
114
(02)
: 119
-
125
[8]
The yields of some organolithium compounds by the improved procedure
Gilman, H
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Gilman, H
Zoellner, EA
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Zoellner, EA
Selby, WM
论文数:
0
引用数:
0
h-index:
0
机构:
Iowa State Coll, Chem Lab, Ames, IA USA
Iowa State Coll, Chem Lab, Ames, IA USA
Selby, WM
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1933,
55
: 1252
-
1257
[9]
IVIN KJ, 1978, CHEM COMMUN, P604
[10]
DYNAMIC INTERLIGAND HYDROGEN TRANSFER IN SOME ETA5-CYCLOPENTADIENYLZIRCONIUM AND ETA-5-CYCLOPENTADIENYLHAFNIUM TETRAHYDROBORATES
MARKS, TJ
论文数:
0
引用数:
0
h-index:
0
机构:
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
MARKS, TJ
KOLB, JR
论文数:
0
引用数:
0
h-index:
0
机构:
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60201
KOLB, JR
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1975,
97
(12)
: 3397
-
3401
←
1
2
3
→