SOLVENT EFFECTS ON THE SIDE SELECTIVITY OF SINGLET OXYGEN WITH ALPHA, BETA-UNSATURATED ESTERS - NEW EVIDENCE FOR A PEREPOXIDE INTERMEDIATE

被引：29

作者：

ORFANOPOULOS, M

STRATAKIS, M

机构：

[1] Department of Chemistry, University of Crete, 71110 Iraklion, Crete

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 49期

关键词：

D O I：

10.1016/0040-4039(91)80509-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The side selectivity of the ene reaction of singlet oxygen with alpha,beta-unsaturated esters depends on solvent polarity. These results are consonant with the formation of a perepoxide intermediate in the limiting step, of the title reaction.

引用

页码：7321 / 7324

页数：4

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