FUNCTIONALITY TRANSFER FROM C(8) TO C(9) IN SESQUITERPENES - SYNTHESIS OF THE NAMED HERBOLIDE-E FROM ARTEMISIN

被引：4

作者：

BLAY, G ^{[1
]}

CARDONA, L ^{[1
]}

GARCIA, B ^{[1
]}

PEDRO, JR ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM ORGAN,E-46100 BURJASSOT,SPAIN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)79147-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The key intermediate 6 was obtained in five steps from artemisin (1). The spectroscopic characteristics of the synthetic product 7a reveal that the proposed structure for the natural herbolide E must be revised.

引用

页码：5253 / 5256

页数：4

共 25 条

[1] SYNTHESIS OF SOME NOVEL TRIFLUOROMETHANESULFONATES AND THEIR REACTIONS WITH ALCOHOLS [J].

BEARD, CD ;

BAUM, K ;

GRAKAUSK.V .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (21) :3673-3677

[2] FUNCTIONALITY TRANSFER FROM C-6 TO C-8 IN SESQUITERPENES - SYNTHESIS OF 8-EPI-IVANGUSTIN AND 8-EPI-ISOIVANGUSTIN FROM SANTONIN [J].

BLAY, G ;

CARDONA, ML ;

GARCIA, B ;

PEDRO, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (21) :6172-6175

[3] EUDESMANOLIDES AND COSTIC ACID-DERIVATIVES FROM FLOURENSIA-MACROPHYLLA [J].

BOHLMANN, F ;

JAKUPOVIC, J ;

SCHUSTER, A ;

KING, RM ;

ROBINSON, H .

PHYTOCHEMISTRY, 1984, 23 (07) :1445-1448

[4] NATURALLY-OCCURRING TERPENE DERIVATIVES .405. NEW GERMACRANOLIDES FROM INULA-HETEROLEPIS [J].

BOHLMANN, F ;

GOREN, NA ;

GRENZ, M .

PHYTOCHEMISTRY, 1982, 21 (05) :1166-1168

[5] TOTAL SYNTHESES OF ROTHIN-A AND ROTHIN-B [J].

CARDA, M ;

ARNO, M ;

MARCO, JA .

TETRAHEDRON, 1986, 42 (13) :3655-3662

[6] TI(O-I-PR)4-MEDIATED NUCLEOPHILIC OPENINGS OF 2,3-EPOXY ALCOHOLS - A MILD PROCEDURE FOR REGIOSELECTIVE RING-OPENING [J].

CARON, M ;

SHARPLESS, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (09) :1557-1560

[7] NATURAL SESQUITERPENOIDS [J].

FRAGA, BM .

NATURAL PRODUCT REPORTS, 1988, 5 (05) :497-521

[8] NATURAL SESQUITERPENOIDS [J].

FRAGA, BM .

NATURAL PRODUCT REPORTS, 1986, 3 (03) :273-296

[9] NATURAL SESQUITERPENOIDS [J].

FRAGA, BM .

NATURAL PRODUCT REPORTS, 1985, 2 (02) :147-161

[10] NATURAL SESQUITERPENOIDS [J].

FRAGA, BM .

NATURAL PRODUCT REPORTS, 1987, 4 (05) :473-498

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