REACTIONS OF MERCURIATED POLYSTYRENES WITH BORON HYDRIDES

被引：5

作者：

ELASSIERY, SA ^{[1
]}

DILLINGHAM, KA ^{[1
]}

PONSONBY, A ^{[1
]}

THORPE, FG ^{[1
]}

WAREHAM, RS ^{[1
]}

机构：

[1] UNIV LANCASTER,SCH PHYS & MAT,CTR POLYMER,LANCASTER LA1 4YA,ENGLAND

来源：

EUROPEAN POLYMER JOURNAL | 1993年 / 29卷 / 2-3期

关键词：

D O I：

10.1016/0014-3057(93)90117-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Linear and cross-linked polystyrenes were mercuriated using mercury(II)trifluoracetate in dichloromethane, dioxane, and THF as solvents, and examples of the mercuriated polymers reacted with a range of boron hydrides to give, after hydrolysis, polymers containing boronic acid groups. The extents of mercuriation, and the efficiencies of the transmetallation reaction in which mercury was replaced by boron were compared for different reactants and conditions.

引用

页码：443 / 447

页数：5

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