CARBON VERSUS SULFUR ADDITION OF NUCLEOPHILES TO SULFINES - THE CASE OF AMINES

被引：32

作者：

CERRETA, F

LERIVEREND, C

METZNER, P

机构：

[1] ISMRA UNIV,CNRS,CHIM COMPOSES THIOORGAN LAB,6 BLVD MARECHAL JUIN,F-14050 CAEN,FRANCE

[2] UNIV CEN,F-14050 CAEN,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(00)61689-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of dithioester sulfines 4 with amines leads to thioamides 5. Sulfine 7, obtained from (-)-thiocamphor, reacts with primary amines at room temperature to afford chiral imines 8. Carbophilic addition, instead of thiophilic addition, has thus been evidenced.

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页码：6741 / 6742

页数：2

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