HYDROGEN-PEROXIDE OXYGENATION OF ALKANES CATALYZED BY MANGANESE(III)-TETRAARYLPORPHYRINS - THE REMARKABLE CO-CATALYTIC EFFECT OF LIPOPHILIC CARBOXYLIC-ACIDS AND HETEROCYCLIC BASES

被引：74

作者：

BANFI, S ^{[1
]}

MAIOCCHI, A ^{[1
]}

MOGGI, A ^{[1
]}

MONTANARI, F ^{[1
]}

QUICI, S ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001794

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxygenation of alkanes promoted by 30% H2O2 and catalysed by chemically robust manganese (III)-tetraaryl porphyrins 2-4 is strongly accelerated by addition of small amounts of lipophilic carboxylic acids and lipophilic heterocyclic bases; cycloalkanes are converted into mixtures of alcohols and ketones at a rate of up to 125 turnovers min-1 in CH2Cl2-H2O solution at 0-degree-C.

引用

页码：1794 / 1796

页数：3

共 19 条

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