ELECTROCHEMISTRY OF THE [CU(HDPA)2]2+/+ COUPLE (HDPA = DI-2-PYRIDYLAMINE)

被引：16

作者：

CINQUANTINI, A ^{[1
]}

OPROMOLLA, G ^{[1
]}

ZANELLO, P ^{[1
]}

机构：

[1] UNIV SIENA,DIPARTMENTO CHIM,PIAN MANTELLINI 44,I-53100 SIENNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期

关键词：

D O I：

10.1039/dt9910003161

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The redox potential of the [Cu(Hdpa)2]2+/+ couple (Hdpa = di-2-pyridylamine) has been determined and the associated structural changes correlated with the kinetic parameters for the copper(II)/copper(I) electron transfer. In accordance with the prediction that one-electron reduction of copper(II) complexes of unusual tetrahedral geometry to the corresponding, usually tetrahedral, copper(I) congeners is thermodynamically favoured, the [Cu(Hdpa)2]2+/+ reduction occurs, in poorly co-ordinating nitro-methane solution, at E-degrees' = + 0.19 V (vs. saturated calomel electrode).

引用

页码：3161 / 3163

页数：3

共 22 条

[1]

BAUER D, 1975, ELECTROANALYTICAL CH, V8, P281

[2]

BROWN ER, 1986, PHYSICAL METHODS CHE, V2, pCH4

[3] CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF [(ETA-5-C5H5)2FE]2AS4CL10O2, THE FERROCENIUM SALT OF A COMPLEX OXYCHLOROARSENATE(III) COUNTERION [J].

CHURCHILL, MR ;

LANDERS, AG ;

RHEINGOLD, AL .

INORGANIC CHEMISTRY, 1981, 20 (03) :849-853

[4] METAL-ION BINDING-SITES COMPOSED OF MULTIPLE NITROGENOUS HETEROCYCLES - SYNTHESIS AND SPECTRAL AND STRUCTURAL STUDY OF BIS(2,2',2''-TRIPYRIDYLAMINE)COPPER(II) BIS(TRIFLUOROMETHANESULFONATE) AND ITS BIS(ACETONITRILE) ADDUCT [J].

DEDERT, PL ;

THOMPSON, JS ;

IBERS, JA ;

MARKS, TJ .

INORGANIC CHEMISTRY, 1982, 21 (03) :969-977

[5] BIFERROCENIUM TETRABROMOFERRATE,[(C5H5)FE(C5H4)-(C5H4)FE(C5H5)]FEBR4 - THE X-RAY STRUCTURAL CHARACTERIZATION OF A MIXED-VALENCE COMPOUND [J].

GEIB, SJ ;

RHEINGOLD, AL ;

DONG, TY ;

HENDRICKSON, DN .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 312 (02) :241-248

[6]

Geiger W. E., 1985, PROG INORG CHEM, V33, P275

[7]

GOUGE EM, 1978, INORG CHEM, V17, P270, DOI 10.1021/ic50180a016

[8]

Gray H.B., 1981, COPPER PROTEINS, P1

[9] CRYSTAL AND MOLECULAR STRUCTURE OF BIS-(2, 2-BIPYRIDYLAMINE)COPPER(II) PERCHLORATE [J].

JOHNSON, JE ;

JACOBSON, RA ;

BEINEKE, TA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (10) :1371-&

[10] ELECTRONIC AND ELECTRON SPIN RESONANCE SPECTRA OF COMPLEXES OF COPPER(II) ION WITH DI-(2-PYRIDYL)AMINE [J].

LANCASTE.JC ;

MCWHINNI.WR .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (11) :1742-+

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