SELECTIVE REDUCTION OF SERRULATENOL AS A ROUTE TO SECO-PSEUDOPTEROSIN ANALOGS

被引：7

作者：

COWIN, LM ^{[1
]}

MASSYWESTROPP, RA ^{[1
]}

机构：

[1] UNIV ADELAIDE,DEPT ORGAN CHEM,GPO BOX 498,ADELAIDE,SA 5001,AUSTRALIA

来源：

JOURNAL OF NATURAL PRODUCTS | 1992年 / 55卷 / 12期

关键词：

D O I：

10.1021/np50090a015

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Deoxygenation of serrulatenol [3], from Eremophila rotundifolia, at C-13 and C-18, gave 5,8-dimethoxyserrulatane [12]. Catalytic hydrogenolysis and metal/NH3 cleavage of the allylic carbon-oxygen bond was followed by deoxygenation at C-18 via the tri-n-butylstannane reduction of the C-18 iodo derivative.

引用

页码：1790 / 1794

页数：5

共 9 条

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