ENGINEERING PROTEIN-STRUCTURE FOR ELECTRON-TRANSFER FUNCTION IN PHOTOSYNTHETIC REACTION CENTERS

被引:142
作者
MOSER, CC
DUTTON, PL
机构
关键词
PHOTOSYNTHESIS; REACTION CENTER; ELECTRON TRANSFER; STRUCTURE-FUNCTION RELATIONSHIP;
D O I
10.1016/0005-2728(92)90205-G
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A basic relationship is defined that incorporates the three parameters that effectively modulate the rate of intraprotein electron transfer, namely distance, free energy and reorganization energy. This empirically validated relationship is used to explore the minimal requirements for protein-catalyzed conversion of excited electronic states into stable charge separated states, the essence of photosynthesis.
引用
收藏
页码:171 / 176
页数:6
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