ACETYLENIC DERIVATIVES OF [FE2(CO)6(MU-SE2)] - ACETYLENIC BOND REDUCTION ON A SELENIUM-STABILIZED FE2PT MIXED-METAL COMPLEX

被引：37

作者：

MATHUR, P ^{[1
]}

HOSSAIN, MM ^{[1
]}

DAS, K ^{[1
]}

SINHA, UC ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, DEPT PHYS, BOMBAY 400076, INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 01期

关键词：

D O I：

10.1039/c39930000046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stepwise addition of phenylacetylene and Pt(PPh3)2 across the Se-Se bond of [Fe2(CO)6(mu-Se2)] can be carried out at room temperature; X-ray analysis demonstrates the acetylenic carbon-carbon bond reduction in the mixed-metal complex [(CO)6Fe2Pt(PPh3)2{mu-SeC(Ph)C(H)Se}].

引用

页码：46 / 48

页数：3

共 17 条

[1] CRYSTAL AND MOLECULAR STRUCTURE OF TETRACYANOETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) [J].

BOMBIERI, G ;

FORSELLI.E ;

PANATTON.C ;

GRAZIANI, R ;

BANDOLI, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (08) :1313-&

[2] STEREOCHEMICAL ANALYSIS OF FE2(CO)6(MU-SE2) - DISELENIUM ANALOG OF FE2(CO)6(MU-S2) [J].

CAMPANA, CF ;

LO, FYK ;

DAHL, LF .

INORGANIC CHEMISTRY, 1979, 18 (11) :3060-3064

[3] MOLECULAR STRUCTURES AND PROTON MAGNETIC RESONANCE SPECTRA OF ETHYLENE COMPLEXES OF NICKEL AND PLATINUM [J].

CHENG, PT ;

COOK, CD ;

NYBURG, SC ;

WAN, KY .

INORGANIC CHEMISTRY, 1971, 10 (10) :2210-&

[4] CRYSTAL AND MOLECULAR STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)-(ETHYLENE)PLATINUM, (PPH3)2PTC2H4 [J].

CHENG, PT ;

NYBURG, SC .

CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (06) :912-&

[5]

COTTON FA, 1988, ADV INORG CHEM RAD, P1157

[6] FE2(MU-E2)(CO)6(E=S,SE, AND TE) AS REAGENTS FOR THE PREPARATION OF MIXED-METAL CHALCOGENIDE CLUSTERS [J].

DAY, VW ;

LESCH, DA ;

RAUCHFUSS, TB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (05) :1290-1295

[7] ADDITION OF ALKYNES TO THE MU-3 BRIDGE ELEMENTS OF (MU-3-X)2FE3(CO)9 (X = RP, SE, TE) [J].

FASSLER, T ;

BUCHHOLZ, D ;

HUTTNER, G ;

ZSOLNAI, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 369 (03) :297-308

[8]

Hartley F. R, 1982, COMPREHENSIVE ORGANO, P471

[9] SYNTHESIS AND CHARACTERIZATION OF NOVEL SELENIUM-CONTAINING CLUSTERS - CRYSTAL-STRUCTURES OF [RU4(MU-4-SE)2(CO)8(MU-CO)3] AND [RU3(MU-3-SE)2(CO)7(PH2P(CH2)3PPH2)] [J].

JOHNSON, BFG ;

LAYER, TM ;

LEWIS, J ;

MARTIN, A ;

RAITHBY, PR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 429 (03) :C41-C45

[10] MECHANISMS OF PHENYLACETYLENE POLYMERIZATION BY MOLYBDENUM AND TITANIUM INITIATORS [J].

KATZ, TJ ;

HACKER, SM ;

KENDRICK, RD ;

YANNONI, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (07) :2182-2183

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