SEMIBUCKMINSTERFULLERENE - MNDO STUDY OF A HEMISPHERICAL TRIINDENOTRIPHENYLENE

被引：36

作者：

FAUST, R

VOLLHARDT, KPC

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 19期

关键词：

D O I：

10.1039/c39930001471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Semiempirical geometry optimization of triindenotriphenylene predicts a rigid cup-shaped structure with strain-induced bond alternation in the central benzenoid ring; model studies of the corresponding Li complex suggest that metal coordination occurs preferentially from the convex side of the bowl.

引用

页码：1471 / 1473

页数：3

共 17 条

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