SAMARIUM IODIDE INDUCED INTRAMOLECULAR C-GLYCOSIDE FORMATION - EFFICIENT RADICAL FORMATION IN THE ABSENCE OF AN ADDITIVE

被引：92

作者：

MAZEAS, D ^{[1
]}

SKRYDSTRUP, T ^{[1
]}

DOUMEIX, O ^{[1
]}

BEAU, JM ^{[1
]}

机构：

[1] UNIV ORLEANS,BIOCHIM STRUCT LAB,URA 499,F-45067 ORLEANS 02,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 13期

关键词：

D O I：

10.1002/anie.199413831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With pyridylsulfonyl instead of phenylsulfonyl leaving groups sugar derivatives such as 1 undergo radical cyclization promoted by SmI2. 5‐exo Cyclization finally results in C‐glycosides of type 2. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1383 / 1386

页数：4

共 33 条

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