SOFT-CHEMICAL SYNTHESIS OF NEW NONLINEAR-OPTICAL MATERIALS, K(0.5)M(0.5)TI(0.5)OPO(4) (M=NB, TA), RELATED TO KTIOPO4

被引：4

作者：

RANGAN, KK

PRASAD, BR

SUBRAMANIAN, CK

GOPALAKRISHNAN, J

机构：

[1] INDIAN INST SCI,SOLID STATE & STRUCT CHEM UNIT,BANGALORE 560012,KARNATAKA,INDIA

[2] INDIAN INST SCI,DEPT PHYS,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soft-chemical oxidation of KTiOPO4-like KM(0.5)(V)Ti(0.5)(III)OPO(4) (M = Nb, Ta) using chlorine in CHCl3 is accompanied by partial deintercalation of potassium, yielding K(0.5)MV(0.5)Ti(0.5)(IV)OPO(4) compounds which are new non-linear optical materials that exhibit efficient second-harmonic generation of 1064 nm radiation, as does KTiOPO4.

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页码：141 / 142

页数：2

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