PREPARATION OF ALPHA-METHYLENE KETONES BY THE PALLADIUM-CATALYZED DECARBOXYLATION-DEACETOXYLATION OF ALLYL ALPHA-ACETOXYMETHYL-BETA-KETO CARBOXYLATES UNDER MILD CONDITIONS

被引：34

作者：

TSUJI, J

NISAR, M

MINAMI, I

机构：

来源：

TETRAHEDRON LETTERS | 1986年 / 27卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)84562-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：2483 / 2486

页数：4

共 10 条

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[4]

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[6] PALLADIUM-CATALYZED DECARBOXYLATION-DEHYDROGENATION OF ALLYL BETA-KETO CARBOXYLATES AND ALLYL ENOL CARBONATES AS A NOVEL SYNTHETIC METHOD FOR ALPHA-SUBSTITUTED ALPHA,BETA-UNSATURATED KETONES [J].

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[7] PALLADIUM-CATALYZED REARRANGEMENT OF ALLYLIC ESTERS OF ACETOACETIC ACID TO GIVE GAMMA,DELTA-UNSATURATED METHYL KETONES [J].

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[8] FACILE GENERATION OF A REACTIVE PALLADIUM(II) ENOLATE INTERMEDIATE BY THE DECARBOXYLATION OF PALLADIUM(II) BETA-KETOCARBOXYLATE AND ITS UTILIZATION IN ALLYLIC ACYLATION [J].

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[9] ENONE FORMATION FROM ALLYL BETA-KETO-ESTERS, ALKENYL ALLYL CARBONATES, SILYL ENOL ETHERS, AND ENOL ACETATES BY THE PHOSPHINE-FREE PALLADIUM CATALYST [J].

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CHEMISTRY LETTERS, 1984, (07) :1133-1136

[10] FACILE PALLADIUM-CATALYZED DECARBOXYLATION REACTION OF ALLYLIC BETA-KETO-ESTERS [J].

TSUJI, J ;

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