CLASSICAL TRANSITION-STATE THEORY IS EXACT IF THE TRANSITION-STATE IS UNIQUE

被引:127
作者
PECHUKAS, P [1 ]
POLLAK, E [1 ]
机构
[1] WEIZMANN INST SCI,DEPT CHEM PHYS,REHOVOT 76100,ISRAEL
关键词
D O I
10.1063/1.438575
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Under mild conditions on the long-range behavior of the potential, we show that classical transition state theory is exact at energy E for a collinear atom-diatom reaction if there is only one candidate for transition state at energy E-that is, only one periodic vibration of energy E across the interaction region. © 1979 American Institute of Physics.
引用
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页码:2062 / 2068
页数:7
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