CLASSICAL TRANSITION-STATE THEORY IS EXACT IF THE TRANSITION-STATE IS UNIQUE

被引：127

作者：

PECHUKAS, P ^{[1
]}

POLLAK, E ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT CHEM PHYS,REHOVOT 76100,ISRAEL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 05期

关键词：

D O I：

10.1063/1.438575

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Under mild conditions on the long-range behavior of the potential, we show that classical transition state theory is exact at energy E for a collinear atom-diatom reaction if there is only one candidate for transition state at energy E-that is, only one periodic vibration of energy E across the interaction region. © 1979 American Institute of Physics.

引用

页码：2062 / 2068

页数：7

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