EXTERNAL HEAVY-ATOM EFFECT ON INTRA-MOLECULAR INTERSYSTEM CROSSING IN A SUPERSONIC BEAM

被引:86
作者
AMIRAV, A
EVEN, U
JORTNER, J
机构
[1] Department of Chemistry, Tel-Aviv University, Tel Aviv
关键词
D O I
10.1016/0009-2614(79)87095-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the enhancement of the S1 → T1 intersystem crossing in van der Waals complexes of tetracene (T) with Kr and with Xe, which are studied by time and energy resolved laser spectroscopy in seeded supersonic beams. This external heavy atom effect is essentially due to single-pair TKr interactions. © 1979.
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页码:9 / 12
页数:4
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