FERROCENE-ATTACHED L-LYSINE POLYMERS AS MEDIATORS FOR GLUCOSE-SENSING ELECTRODES

被引：25

作者：

IIJIMA, S ^{[1
]}

MIZUTANI, F ^{[1
]}

YABUKI, S ^{[1
]}

TANAKA, Y ^{[1
]}

ASAI, M ^{[1
]}

KATSURA, T ^{[1
]}

HOSAKA, S ^{[1
]}

IBONAI, M ^{[1
]}

机构：

[1] KOGAKUIN UNIV,FAC ENGN,DEPT IND CHEM,SHINJUKU KU,TOKYO 160,JAPAN

来源：

ANALYTICA CHIMICA ACTA | 1993年 / 281卷 / 03期

关键词：

AMPEROMETRY; BIOSENSORS; ENZYMATIC METHODS; ENZYME ELECTRODES; FERROCENE; GLUCOSE; LYSINE POLYMERS; POLYMERIC MEDIATORS;

D O I：

10.1016/0003-2670(93)85006-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Two kinds of water-soluble polymers having ferrocenyl groups were prepared by the reactions of ferrocenoyl chloride with a homopolymer and a copolymer of L-lysine. The polymers acted as electron mediators between electrodes and the reduced form of glucose oxidase. Amperometric glucose-sensing electrodes were constructed by the simultaneous immobilization of each polymeric mediator and glucose oxidase near the surface of a glassy carbon electrode with a semipermeable membrane. The sensing-electrode using the ferrocene-attached L-lysine homopolymer was usable for the determination of glucose concentrations up to 6 mM.

引用

页码：483 / 487

页数：5

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