SYNTHETIC STUDIES ON THAXTOMIN-A AND THAXTOMIN-B, PHYTOTOXINS ASSOCIATED WITH STREPTOMYCES-SCABIES, THE CAUSAL ORGANISM OF POTATO COMMON SCAB

被引：23

作者：

GELIN, J

MORTIER, J

MOYROUD, J

CHENE, A

机构：

[1] RHONE POULENC SECTEUR AGRO,CTR RECH DARGOIRE,BP 9163,F-69263 LYON 09,FRANCE

[2] RHONE POULENC AG CO,RES TRIANGLE PK,NC 27709

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 13期

关键词：

D O I：

10.1021/jo00065a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preliminary results of a study on the stereocontrolled racemic synthesis of thaxtomins A and B are disclosed. The synthesis features a new C-C bond-forming reaction: dilithium tetrachlorocuprate was shown to be an efficient catalyst for cross-coupling reactions of lithiated 1,4-dialkyl-2,5-piperazinedione anions with gramine methosulfate and alkyl halides.

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页码：3473 / 3475

页数：3

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