PALLADIUM-CATALYZED REGIOSELECTIVE CYCLIZATION OF UNSATURATED BROMOANILINOALKENENITRILES

被引：35

作者：

YANG, CC ^{[1
]}

SUN, PJ ^{[1
]}

FANG, JM ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 107,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002629

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha-(o-Bromoanilino)alkenenitriles are converted to 2-(methylamino)benzonitrile and varied gamma-carbolines by catalysis with palladium; the reactions may involve intramolecular aryl additions to the cyano group and other processes such as cyano group transposition, electrocyclisation, ethyl group transfer and oxidative aromatisation.

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页码：2629 / 2630

页数：2

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