ACYLATED 2-OXOGLYCOSYL BROMIDES - EXPLORATION OF THEIR REACTION POTENTIAL

被引：25

作者：

LICHTENTHALER, FW

SCHWIDETZKY, S

NAKAMURA, K

机构：

[1] Institut für Organische Chemie, Technische Hochschule Darmstadt

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)94336-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acylated glycos-2-ulosyl bromides give a variety of useful ensuing reactions, preparatively most relevant being their smooth α- and β-selective glycosidation, their reduction to glucosyl bromides with a free 2-OH, and their C-homologation to higher-carbon sugars. © 1990.

引用

页码：71 / 74

页数：4

共 11 条

[1]

Cuny E., 1983, ANGEW CHEM, V95, P906

[2]

GIESE B, 1987, ORG SYNTH, V65, P236

[3]

Lichtenthaler F. W., 1982, ANGEW CHEM, V94, P643

[4] SUGAR ENOLONES .16. FUNCTIONALIZATION AT PROANOMERIC CENTERS BY PHOTOBROMINATION - A NOVEL ACCESS TO OXO-GLYCOSYL AND ACYLOXYIMINO-GLYCOSYL BROMIDES [J].