UNUSUALLY HIGH ASYMMETRIC INDUCTION IN THE PHOTO-CHEMICAL FORMATION OF OXETANES

被引：27

作者：

GOTTHARDT, H

LENZ, W

机构：

[1] Gasamthochschule Wuppertal, D-5600

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric reactions giving products of high enantiomeric purity are of topical interest in synthetic chemistry. An example is the addition of ()‐menthyl phenylglyoxylate 1 to dimethylbutene. The product consists of 76.3% of one diastereomer and 23.7% of the other. i.e. its enantiomeric purity is 53% (R()‐C10H19). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：868 / 868

页数：1