FACILE P-C BOND-CLEAVAGE IN BIS(DIPHENYLPHOSPHINO)METHANE WITH THE FORMATION OF NEW PT(II) P, S-CHELATES CONTAINING A P-N BOND

被引：9

作者：

OKEYA, S ^{[1
]}

SHIMOMURA, H ^{[1
]}

KUSHI, Y ^{[1
]}

机构：

[1] INST MOLEC SCI, COORDINAT CHEM LAB, OKAZAKI, AICHI 444, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.2019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New platinum(II) P, S-chelates, [(dppm-H)PtP(Ph)2N(R)C(=NR)S] (R=o-tolyl or Et(2b)), were prepared by a reaction of [Pt(dppm-H)2] with 1,3-disubstituted thioureas. A reaction intermediate, [(dppm)PtN(R)C(=NR)S] (R=o-tol), was isolated. Crystallographic X-ray analysis for 2b revealed a P, S-chelated structure containing a P-N bond.

引用

页码：2019 / 2022

页数：4

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