METAL-INDUCED STERIC CONTROL OF BIS-PARACYCLOPHANE CONFORMATION

被引：22

作者：

HEIRTZLER, FR

HOPF, H

JONES, PG

BUBENITSCHEK, P

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ORGAN CHEM,D-38106 BRAUNSCHWEIG,GERMANY

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN CHEM,BRAUNSCHWEIG,GERMANY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 08期

关键词：

D O I：

10.1016/0040-4039(94)02485-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ligand 2 and its bis-silver(I) complexes 4 were investigated by H-1 and C-13 NMR spectroscopy, X ray crystallography and molecular mechanics calculations. We conclude that 2 adopts a conformation in solution and in the solid stale in which the two [2.2.2]paracyclophanyl groups are syn, whereas 4 displays an anti-conformation.

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页码：1239 / 1242

页数：4

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