NEW PHASE FORMATION IN HETERO-STRUCTURED MULTILAYERS OF TRICOSA-2,4-DIYNOIC ACID AND ARACHIDIC ACID

被引:5
作者
OKADA, S [1 ]
NAKANISHI, H [1 ]
MATSUDA, H [1 ]
KATO, M [1 ]
SUGI, M [1 ]
SAITO, M [1 ]
IIZIMA, S [1 ]
机构
[1] ELECTROTECH LAB,TSUKUBA,IBARAKI 305,JAPAN
关键词
CADMIUM COMPOUNDS - FILMS - Structure - SALTS;
D O I
10.1295/polymj.20.493
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Four different types of hetero-structured multilayers of tricosa-2,4-diynoic acid (18-0ADA) and arachidic acid (C//2//0CA) in cadmium salts were prepared, and the structures and polymerization behavior of 18-0ADA in such hetero-multilayers were compared with those in the multilayers of pure 18-0ADA. A new phase of 18-0ADA was found in the multilayers having hydrophilic interactions with C//2//0CA, whereas in the multilayers having hydrophilic interactions by themselves new and original phases were mixed up. To clarify these phenomena, the structures of the same types of hetero-multilayers of fatty acids were also investigated, and no new phases were found for the fatty acids.
引用
收藏
页码:493 / 497
页数:5
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