ELECTRONIC-STRUCTURE OF THE ORGANIC CONDUCTOR (DME-DCNQI)2CU STUDIED BY PHOTOEMISSION SPECTROSCOPY

被引：6

作者：

INOUE, IH

KAKIZAKI, A

KOBAYASHI, A

KATO, R

KOBAYASHI, H

NAMATAME, H

FUJIMORI, A

机构：

[1] TOHO UNIV,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

[2] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN

[3] UNIV TOKYO,DEPT PHYS,BUNKYO KU,TOKYO 113,JAPAN

[4] UNIV TOKYO,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

PHYSICA C | 1991年 / 185卷

关键词：

D O I：

10.1016/0921-4534(91)91467-I

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

An x-ray photoemission study of (DMe-DCNQI)2Cu is reported. The line-shape analysis reveals the mixed valency of Cu+ and Cu2+, and the Cu+:Cu2+ ratio is found to be approximately 2:1. This suggest that Cu is in a valance fluctuating state in the metallic state and, in other (DCNQI)2Cu compounds, a Cu+-Cu2+ charge-ordering takes place below the metal-insulator transition temperature.

引用

页码：2691 / 2692

页数：2

共 3 条

[1]

INOUE I, IN PRESS

[2] THE ORGANIC PI-ELECTRON METAL SYSTEM WITH INTERACTION THROUGH MIXED-VALENCE METAL CATION - ELECTRONIC AND STRUCTURAL-PROPERTIES OF RADICAL SALTS OF DICYANO-QUINODIIMINE, (DME-DCNQI)2CU AND (MECL-DCNQI)2CU [J].