KINETICS AND MECHANISM OF OXIDATION OF URIC-ACID BY HEXACYANOFERRATE(III) IN ACETATE BUFFERS

被引：2

作者：

AGRAWAL, A ^{[1
]}

SHARMA, N ^{[1
]}

MISHRA, SK ^{[1
]}

SHARMA, PD ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1992年 / 17卷 / 06期

关键词：

D O I：

10.1007/BF02910755

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The second order kinetics of uric acid oxidation by hexacyanoferrate(III) in acetate buffers were studied by estimating oxidant colorimetrically at 420 nm. Two moles of organic acid react with one mole of the oxidant and oxidation products are alloxan and urea.

引用

页码：547 / 551

页数：5

共 26 条

[1] ELECTRON TRANSFER PROCESSES AND THE OXIDATION-REDUCTION REACTIONS OF HEXACYANOFERRATE(III) ION IN AQUEOUS SOLUTION [J].

ADAMSON, AW .

JOURNAL OF PHYSICAL CHEMISTRY, 1952, 56 (07) :858-862

[2]

BERKA A, 1965, NEWER REDOX TITRANTS, P18

[3] METAL-ION CATALYSIS IN SOME REACTIONS OF HEXACYANOFERRATE(III) IONS .2. OXIDATION OF CYSTEINE AND RELATED THIOLS IN PRESENCE OF ETHYLENEDIAMINETETRA-ACETIC ACID [J].

BRIDGART, GJ ;

WILSON, IR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (12) :1281-1284

[4]

Brunaud M, 1969, Therapie, V24, P785

[5]

BUCHANAN JM, 1958, ENZYMATIC SYNTHESIS, V54, P104

[6]

Davies C.W., 1962, ION ASS

[7]

FREW JE, 1985, ANAL LETT PT B, V18, P1579

[8]

Gleu K., 1933, Z ANAL CHEM, V95, P305

[9]

HUTCHINGS GH, 1978, URIC ACID

[10] The oxidation potential of the system potassium ferrocyanide-potassium ferricyanide at various ionic strengths [J].

Kolthoff, IM ;

Tomsicek, WJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1935, 39 (07) :945-954

← 1 2 3 →