LIQUID-CRYSTALLINE D-GLUCOSE DIALKYL ACETALS AND DODECYL D-GLUCOFURANOSIDES

被引：24

作者：

TIETZE, LF ^{[1
]}

BOGE, K ^{[1
]}

VILL, V ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ORGAN CHEM,D-20146 HAMBURG,GERMANY

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 06期

关键词：

ACETALS; AMPHIPHILES; CARBOHYDRATES; GLUCOSIDES; LIQUID CRYSTALS;

D O I：

10.1002/cber.19941270615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new systems of liquid crystalline glucose derivatives 5a-d, 6a, b are prepared, studied and compared with reference compounds. The alpha- and beta-D-dodecyl glucofuranosides 6a, b show smectic A phases. The clearing points of the furanosides are of the same magnitude as those of the pyranosides. The alkyl glucose acetals 5a-d show columnar discotic phases. The clearing points are about 30-degrees-C lower than those of the corresponding thioacetals.

引用

页码：1065 / 1068

页数：4

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