SYNTHESIS OF 2H,2H-PERFLUOROALKYL AND 2H-PERFLUOROALKENYL CARBOXYLIC-ACIDS AND AMIDES

被引：51

作者：

ACHILEFU, S ^{[1
]}

MANSUY, L ^{[1
]}

SELVE, C ^{[1
]}

THIEBAUT, S ^{[1
]}

机构：

[1] UNIV NANCY 1,CNRS,LESOC,UA 406,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 70卷 / 01期

关键词：

SYNTHESIS; 2-PERFLUOROALKYL ETHANOIC ACIDS; JONES REAGENT; NMR SPECTROSCOPY; IR SPECTROSCOPY;

D O I：

10.1016/0022-1139(94)03084-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient and convenient procedure for the synthesis of 2-perfluoroalkyl ethanoic acids by direct oxidation of 2-perfluoroalkyl ethanols with Jones' reagent (CrO3/H2SO4) is described. Treatment of the acids with aqueous sodium hydroxide gave 3-perfluoroalkyl, 3-fluoro-2,3-propenyl carboxylic acids which may be used for the preparation of the corresponding chlorides and amides.

引用

页码：19 / 26

页数：8

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