PICOSECOND TIME-DEPENDENT STOKES SHIFT STUDIES OF FLUOROPROBE IN LIQUID SOLUTION

被引：31

作者：

MIDDELHOEK, ER ^{[1
]}

VANDERMEULEN, P ^{[1
]}

VERHOEVEN, JW ^{[1
]}

GLASBEEK, M ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ORGAN CHEM LAB,1018 WS AMSTERDAM,NETHERLANDS

来源：

CHEMICAL PHYSICS | 1995年 / 198卷 / 03期

关键词：

D O I：

10.1016/0301-0104(95)00219-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on a picosecond spectroscopic study of the dynamical Stokes shift of fluoroprobe in the lowest excited state in the solvents diethylether and ethylacetate. Time-resolved emission spectra with a time-resolution of approximately 10 ps are presented. The spectra reflect dynamical Stokes shifts of a few thousand wave numbers within 10-100 ps after the pulsed laser excitation. The time-dependent shifts are representative of the solvation dynamics of fluoroprobe in diethylether and ethylacetate.

引用

页码：373 / 380

页数：8

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