NOVEL LIGAND ORIENTATIONS IN PYRIDINE AND IMIDAZOLE COMPLEXES OF A HIGHLY SUBSTITUTED NONPLANAR PORPHYRIN, AND IMPLICATIONS FOR THE DESIGN OF PORPHYRINS AS REGIO-SPECIFIC AND STEREO-SPECIFIC OXIDATION CATALYSTS

被引：26

作者：

MEDFORTH, CJ

MUZZI, CM

SMITH, KM

ABRAHAM, RJ

HOBBS, JD

SHELNUTT, JA

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

[2] SANDIA NATL LABS,DEPT FUEL SCI 6211,ALBUQUERQUE,NM 87185

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Specific orientations are observed for pyridine and imidazole ligands complexed to a highly substituted nonplanar porphyrin, suggesting that suitably designed nonplanar porphyrins might be used to direct substrates and increase regio- and stereo-specificity in porphyrin catalysed oxidation reactions.

引用

页码：1843 / 1844

页数：2

共 20 条

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