PERMETHYLTITANOCENE TELLURIDES AND DITELLURIDES - X-RAY STRUCTURES OF [(C(5)ME(5))(2)TI](2)(MU-TE) AND (C(5)ME(5))(2)TI(ETA(2)-TE-2)

被引：25

作者：

FISCHER, JM

PIERS, WE

MACGILLIVRAY, LR

ZAWOROTKO, MJ

机构：

[1] UNIV GUELPH,GUELPH WATERLOO CTR GRAD WORK CHEM,DEPT CHEM & BIOCHEM,GUELPH,ON N1G 2W1,CANADA

[2] ST MARYS UNIV,DEPT CHEM,HALIFAX,NS B3H 3C3,CANADA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 10期

关键词：

D O I：

10.1021/ic00114a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes with ''naked'' main group elements acting as ligands continue to attract a great deal of interest. Reported herein are the syntheses and structures of a telluride and a ditelluride derivative of permethyltitanocene and their interconversion. The eta(2)-ditelluride is a rare example of this type of complex and may be employed as a ''Te-2'' transfer agent when treated with some alkyl halides.

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页码：2499 / 2500

页数：2

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