The formation of CH radicals in hydrocarbon atom flames

被引：20

作者：

Becker, K. H. ^{[1
]}

Kley, D. ^{[1
]}

机构：

[1] Univ Bonn, Inst Phys Chem, D-5300 Bonn, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 02期

关键词：

D O I：

10.1016/0009-2614(69)85067-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The support for the reaction CH + O-2 --> OH* + CO and CH + O --> CHO+ e from former work and the conclusion from this work that the precursor of CH in several hydrocarbon-atom flames cannot be a hydrogen-containing radical have led to the proposal of C2O + H --> CH + CO as the main source of CH in atom flames. The possibility of this mechanism for hot hydrocarbon combustion has been discussed.

引用

页码：62 / 64

页数：3

共 40 条

[1] REACTION OF ATOMIC OXYGEN WITH ACETYLENE .2. CHEMI-IONIZATION AND CHEMILUMINESCENCE
ARRINGTON, CA
BRENNEN, W
GLASS, GP
MICHAEL, JV
NIKI, H
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (05) : 1489 - +
[2] Becker K. H., 1969, MOL LUMINESCENCE, P509
[3] CO EMISIION FROM ACETYLENE-OXYGEN FLAMES
BECKER, KH
BAYES, KD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (01) : 396 - &
[4] CO CHEMILUMINESCENCE FROM FLAMES
BECKER, KH
BAYES, KD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (02) : 653 - &
[5] BECKER KH, 1969, S COMB U POIT 1968 C
[6] ABSORPTION AND EMISSION MEASUREMENTS OF C2 AND CH ELECTRONIC BANDS IN LOW-PRESSURE OXYACETYLENE FLAMES
BLEEKRODE, R
NIEUWPOORT, WC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (10P1) : 3680 - +
[7] ESR STUDIES OF REACTIONS OF ATOMIC OXYGEN AND HYDROGEN WITH SIMPLE HYDROCARBONS
BROWN, JM
THRUSH, BA
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (531P): : 630 - &
[8] BULEWICZ EM, 1963, 9 INT S COMB, P638
[9] CALCOTE HF, 1965, AGARD SPECIAL PUBL, V8, P1
[10] CALCOTE HF, 1965, 10 S INT COMB, P605

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