VIBRATIONAL-RELAXATION OF OXYGEN - STATE TO STATE RATE CONSTANTS

被引：108

作者：

BILLING, GD

KOLESNICK, RE

机构：

[1] Department of Chemistry, H.C. Ørsted Institute, University of Copenhagen

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 200卷 / 04期

关键词：

D O I：

10.1016/0009-2614(92)87008-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A semi-classical collision model has been used to calculate V-V (vibration-vibration) and V-T/R (vibration-translation/rotation) rate constants for vibrational transitions in oxygen. The potential energy surface is obtained from a recent atom-atom fit to ab initio data. In the semi-classical model used the translational and rotational motion of the two molecules is treated classically whereas the vibrational motion of both molecules is quantized.

引用

页码：382 / 386

页数：5

共 11 条

[1] ROTATIONAL AND VIBRATIONAL-RELAXATION OF HYDROGEN AND DEUTERIUM [J].