STEREOCHEMICAL NONRIGIDITY IN A CHELATED PLATINUM(0)-DIOLEFIN COMPLEX

被引：12

作者：

BASSINDALE, AR

BROWN, SSD

LO, P

机构：

[1] DOW CORNING LTD,BARRY CF6 7YL,S GLAM,WALES

[2] DOW CORNING CORP,MIDLAND,MI 48686

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereochemical nonrigidity has been observed in the Pt(0) complex [Pt{(eta-ViMe2Si)201(P(t)Bu3)] (1a) by NMR spectroscopy. The activation parameters have been measured by DNMR3 analysis of the spectra over a range of temperatures. It is concluded that the vinylsiloxane ligand is undergoing a facile dissociation-reassociation process, although a related nondissociative mode involving a rotation about the alkene C-C axis cannot be completely dismissed.

引用

页码：738 / 740

页数：3

共 15 条

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