UNUSUAL INTERACTION OF AG+ WITH AN ORGANOPALLADIUM CROWN-ETHER - SYNTHESIS AND STRUCTURES OF [PDCL(L)] AND [PD(H2O)(L)(AG)][CF3SO3](2) (L=5,8,11-TRIOXA-2,14-DITHIA[15]-M-CYCLOPHANE)

被引：47

作者：

KICKHAM, JE ^{[1
]}

LOEB, SJ ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR,ON N9B 3P4,CANADA

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 2 equiv of [Ag][CF3SO3] with the organopalladium crown ether [PdCl(L)] (L = 5,8,11-trioxa-2,14-dithia[l5]-m-cyclophane) results in formation of AgCl and encapsulation of the second Ag+ ion to form the bimetallic complex [Pd(H2O)(L)(Ag)][CF3SO3](2). The X-ray structure of [Pd(H2O)(L)(Ag)][CF3SO3]2 . CH2Cl2 shows that the electrophilic Ag+ ion is bound to the Pd-C(aryl) unit and that this interaction is complemented by peripheral coordination to the ether oxygens and a counterion.

引用

页码：3584 / 3587

页数：4

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