THERMAL DECOMPOSITION OF DIMSYL ION IN DIMETHYL SULFOXIDE

被引:15
作者
PRICE, CC
YUKUTA, T
机构
[1] Department of Chemistry, University of Pennsylvania, Philadelphia
关键词
D O I
10.1021/jo01261a004
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The decomposition of sodium dimsyl in dimethyl sulfoxide at temperatures above 80° produces a mixture of methylated butadienes and a white precipitate which, by titration and reaction with benzyl chloride, is evidently a mixture of sodium methanesulfenate, sodium methanesulfinate, and sodium methylmercaptide. © 1969, American Chemical Society. All rights reserved.
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页码:2503 / &
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