OXYMETALATION .22. HYDROPEROXYMERCURIATION USING 30-PERCENT HYDROGEN-PEROXIDE

被引：7

作者：

BLOODWORTH, AJ

SPENCER, MD

机构：

[1] Chemistry Department, University College, London, London, WC1H 0AJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)80002-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Each of eleven representative alkenes, R1R2CCHR3, has been found to react with an equimolar amount of mercury(II) acetate in about an eightfold excess of 30% aqueous hydrogen peroxide to afford the hydroperoxymercurial, R1R2C(OOH)-CH(HgOAc)R3, or a mixture of the hydroperoxymercurial and the corresponding hydroxymercurial, R1R2C(OH)CH(HgOAc)R3, which can be separated by column chromatography (SiO2, CH2Cl2). Eight new hydroperoxymercurials have been characterized. © 1990.

引用

页码：299 / 304

页数：6

共 5 条

[1] OXYMETALATION .16. MODIFIED PROCEDURES FOR REDUCING PEROXYMERCURIALS - CONVERSION OF NON-TERMINAL ALKENES INTO SECONDARY ALKYL TERT-BUTYL PEROXIDES
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[2] OXYMETALATION .10. SYNTHESIS OF BETA-MERCURIOALKYL HYDROPEROXIDES AND BIS-BETA-MERCURIOALKYL PEROXIDES FROM HYDROGEN-PEROXIDE
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[3] OXYMETALATION .21. REGIOSELECTIVITY, REARRANGEMENT, AND DIRECT 1,2-DIOXOLANE FORMATION IN THE PEROXYMERCURIATION OF CIS-1,2-DIPHENYLCYCLOPROPANE AND TRANS-1,2-DIPHENYLCYCLOPROPANE
BLOODWORTH, AJ
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[4] PEROXYMERCURIZATION OF OLEFINS
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[5] SOKOLOV VI, 1972, B ACAD SCI USSR CH+, P1089

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