TEMPERATURE-DEPENDENCE OF THE COLLISIONAL DEACTIVATION OF I(2P1/2) BY I2 AND O2 FROM 300-K TO 600-K

被引：20

作者：

BURDE, DH ^{[1
]}

YANG, TT ^{[1
]}

MCFARLANE, RA ^{[1
]}

机构：

[1] HUGHES RES LABS, MALIBU, CA 90265 USA

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 205卷 / 01期

关键词：

D O I：

10.1016/0009-2614(93)85168-N

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The collisional deactivation of excited iodine atoms I(5p5 P-2(1/2)) by I2 and O2 has been studied as a function of temperature from 295 to 600 K. The decay of the excited iodine atom concentration following dye laser photolysis of molecular I2 was detected by time-resolved fluorescence at 1.315 mum. The temperature dependence of quenching rate constants by molecular I2 and O2 was found to be weak over this range.

引用

页码：69 / 74

页数：6

共 26 条

[1]

AVIZONIS PV, 1982, GAS FLOW CHEM LASERS

[2]

BORIEV IA, 1985, OPT SPEKTROSK+, V59, P277

[3] ON THE INTERPRETATION OF HALOGEN ATOM RECOMBINATION RATES [J].