ANGULAR-MOMENTUM IN UNIMOLECULAR REACTIONS

被引：8

作者：

KLOTS, CE

机构：

[1] Chemical Physics Section, Oak Ridge National Laboratory, Oak Ridge

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 01期

关键词：

D O I：

10.1063/1.464656

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several formulations may be noted for the role of angular momentum in unimolecular reactions. We use here a generalization of the Rice-Gershinowitz model to exemplify their inter-relations. The equations which emerge are simple and equally applicable to loose and tight transition states. Their predictions are compared with experiment and with more tedious calculations.

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收藏

页码：206 / 210

页数：5

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