COPPER-CATALYZED ALLYLIC ALKYLATIONS OF ALKYLZIRCONIUM INTERMEDIATES

被引：47

作者：

VENANZI, LM

LEHMANN, R

KEIL, R

LIPSHUTZ, BH

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

[2] SWISS FED INST TECHNOL,INORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)61072-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrozirconation of olefins followed by exposure of the resulting alkylzirconium species to catalytic CuCN in the presence of activated halides or phosphonates gives rise to products of alkylation in good yields under mild conditions.

引用

页码：5857 / 5860

页数：4

共 16 条

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