STEREOCONTROLLED FORMATION OF QUATERNARY CARBON CENTERS BY CONJUGATE ADDITION OF LITHIUM ENOLATES OF DIOXANONES TO BETA-BROMOACRYLATES AND BETA-BROMOVINYL SULFONES - DEPENDENCE OF STEREOSELECTIVITY ON ALKENE GEOMETRY

被引：9

作者：

BRUNCKO, M ^{[1
]}

CRICH, D ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM MC111,CHICAGO,IL 60607

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 25期

关键词：

D O I：

10.1021/jo00104a061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[No abstract available]

引用

页码：7921 / 7923

页数：3

共 19 条

[1] (2R)-5-ALKYL-2-TERT-BUTYL-6-METHYL-4H-1,3-DIOXIN-4-ONES AS INTERMEDIATES FOR THE PREPARATION OF ALPHA-BETA-BETA-TRISUBSTITUTED BETA-HYDROXYCARBOXYLIC ACIDS FROM (R)-3-HYDROXYBUTYRIC ACID UNDER SELF-REGENERATION OF THE STEREOGENIC CENTER [J].

AMBERG, W ;

SEEBACH, D .

CHEMISCHE BERICHTE, 1990, 123 (12) :2429-2438

[2]

Angeletti E., 1957, GAZZ CHIM ITAL, V87, P1086

[3] ASYMMETRIC FORMATION OF QUATERNARY CENTERS THROUGH AZA-ANNULATION OF CHIRAL BETA-ENAMINO ESTERS WITH ACRYLATE DERIVATIVES [J].

BARTA, NS ;

BRODE, A ;

STILLE, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (14) :6201-6206

[4] 1,2-STEREOINDUCTION IN RADICAL REACTIONS - STEREOSELECTIVE SYNTHESIS OF 2-ALKYL-3-HYDROXYBUTANOATES [J].

BULLIARD, M ;

ZEHNDER, M ;

GIESE, B .

HELVETICA CHIMICA ACTA, 1991, 74 (07) :1600-1607

[5] THE E/Z GEOMETRY OF THE ENOLATE COMPONENT DETERMINES FACE SELECTION OF THE ALDEHYDE COMPONENT IN CHIRAL DIAZABOROLIDINE-DIRECTED ENANTIOSELECTIVE ALDOL COUPLING [J].

COREY, EJ ;

LEE, DH .

TETRAHEDRON LETTERS, 1993, 34 (11) :1737-1740

[6] ENANTIOSELECTIVE ALDOL CONDENSATIONS .2. ERYTHRO-SELECTIVE CHIRAL ALOL CONDENSATIONS VIA BORON ENOLATES [J].

EVANS, DA ;

BARTROLI, J ;

SHIH, TL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2127-2129

[7]

FUJI K, 1994, CHEM REV, V94, P2037

[8]

HASSNER A, 1978, TETRAHEDRON LETT, P4475

[9]

HORI I, 1979, TETRAHEDRON LETT, P4087

[10]

MAMESCALCHI F, 1979, SYNTHESIS-STUTTGART, P445

← 1 2 →